To quickly get along well with someone.
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To like each other right away and get along easily.
When two people hit it off, the talk flows from the very first minute.
The bond feels natural, with no effort at all.
"Click"
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Very similar — also means to connect instantly; 'hit it off' implies a bit more enthusiasm and warmth
"Bond"
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To develop a close connection — bonding takes time; hitting it off is immediate
"Hit it off"
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To immediately like each other and connect naturally from the very first meeting