To quickly get along well with someone.
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To immediately like each other and get along very well from the start.
When two people hit it off, there's instant chemistry or rapport — conversation flows easily and the connection feels natural and effortless.
"Click"
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Very similar — also means to connect instantly; 'hit it off' implies a bit more enthusiasm and warmth
"Bond"
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To develop a close connection — bonding takes time; hitting it off is immediate
"Hit it off"
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To immediately like each other and connect naturally from the very first meeting